Toxicity Reduction of Polymer-Stabilized Silver Nanoparticles by Sunlight

TitleToxicity Reduction of Polymer-Stabilized Silver Nanoparticles by Sunlight
Publication TypeJournal Article
Year of Publication2011
AuthorsCheng YW, Yin LY, Lin SH, Wiesner MR, Bernhardt ES, Liu J
JournalJournal of Physical Chemistry C
Volume115
Pagination4425-4432
Date PublishedMar 24
ISBN Number1932-7447
Accession Numberhttp://gateway.isiknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=ResearchSoft&SrcApp=EndNote&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000288401200010
KeywordsGOLD, metal nanostructures, nanocrystals, nanoprisms, shape-controlled synthesis, size, WATER
Abstract

The environmental and health impacts of nanomaterials are becoming important topics of research in recent years. The unique advantages offered by these nanomaterials in wide range of applications cannot be realized until these concerns are resolved. Among all the nanomaterials, Ag nanoparticles, due to their existing extensive uses in commercial products, demand immediate attention. Since the nanoparticle suspensions will be exposed to environmental conditions different from a research lab setting, many factors, including light, temperature, salinity, etc., are suspected to affect the stability of the nanoparticle and also their toxicity. In this study, we examined the effect of sunlight on the stability and toxicity of 6 and 25 nm Ag nanoparticles coated with gum arabic (GA) and polyvinylpyrrolidone (PVP). Under sunlight irradiation, all of these nanoparticles irreversibly aggregated to different degrees depending on the surface coating. The UV content of the sunlight is identified to be the driving force of nanoparticle aggregation, and the strong oscillating dipole dipole interaction is believed to be the origin of the destabilization. Toxicity examinations of the nanoparticles to a wetland plant, Lolium multiflorum, indicate that their toxicity is greatly reduced after sunlight irradiation.

URLhttp://gateway.isiknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=ResearchSoft&SrcApp=EndNote&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000288401200010
Alternate JournalJ Phys Chem C